Synthesis of novel thieno[3,2-b]thienobis(silolothiophene) based low bandgap polymers for organic photovoltaics.

نویسندگان

  • Bob C Schroeder
  • Raja Shahid Ashraf
  • Stuart Thomas
  • Andrew J P White
  • Laure Biniek
  • Christian B Nielsen
  • Weimin Zhang
  • Zhenggang Huang
  • Pabitra Shakya Tuladhar
  • Scott E Watkins
  • Thomas D Anthopoulos
  • James R Durrant
  • Iain McCulloch
چکیده

Thieno[3,2-b]thienobis(silolothiophene), a new electron rich hexacyclic monomer has been synthesized and incorporated into three novel donor-acceptor low-bandgap polymers. By carefully choosing the acceptor co-monomer, the energy levels of the polymers could be modulated and high power conversion efficiencies of 5.52% were reached in OPV devices.

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عنوان ژورنال:
  • Chemical communications

دوره 48 62  شماره 

صفحات  -

تاریخ انتشار 2012